Synthesis and Characterization of Immobilized Thiolactic Ligand System for the Detoxification of Tannery Wastewater
DOI:
https://doi.org/10.14738/aivp.85.8790Keywords:
tannery wastewater, detoxification, polysiloxane, thiosalicylic ligand, thermodynamicAbstract
A porous solid polysiloxane immobilized thiosalicylic acid ligand system has been prepared by hydrolytic polycondensation of tetraethylorthosilicate with a mixture of 3-chloropropyltrimethoxysilane, methanol and sodium hydroxide as a catalyst, gelation formed after 40 min. The product formed was functionalized with excess ethylchloroacetate, triethylamine and immobilized with thiosalicylic acid. The immobilized ligand was characterized using FTIR, the spectrum showed characteristic absorption regions (cm-1) at: 3384 (OH), 1587 to 1722 (C=C, C=O); 900 to 1038 (Si - O) respectively. SEM-EDX showed irregular particle sizes of the polysiloxane matrices with elemental composition (wt %): 3-CPPS; Si (50.45), O (25.02) and Cl (24.57). F - 3CPPS showed, O (58.68), Si (41.32); thiolactic (0.00 of S). The competitive sorption characteristic of the metal ions (Cr3+, Fe3+, Pb2+, Cu2+ and Zn2+) were studied using Microwave Plasma Atomic Emission Spectrophotometer (Agilent MPAES-4200). The immobilized thiolactic ligand exhibits high potential for the extraction of heavy metals in tannery wastewater at pH 6.0, this development would improve the treatment of tannery wastewater at a low cost; batch or column systems of extraction of metal could be employed. Thermodynamic range for the parameters with respect to Cr3+, Fe3+, Pb2+, Cu2+ and Zn2+ yielded negative values for ΔGo, (Cu2+ -(8.650 to 11.962) to Fe2+ -(14.368 to 14.842) KJmol-1; positive values for ΔHo: Zn2+ (0.000) to Cu2+ (21.047) KJmol-1 and ΔSo: Zn2+ (47.421) to Fe3+ (245.869) Jmol1K1 respectively, indicating spontaneous, endothermic reactions and high degree of disorderliness with respect to metal ion binding capacity to the ligand system.
References
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(26) Rajashree Kobiraj; Neha Gupta; Atul Kumar Kuswaha; Chattopadhyaya M. C (2012) Determination of Equilibrium, Kinetics and Thermodynamic Parameters for Adsorption of Brilliant Green Dye from Aqueous Solutions onto Eggshell Powder. Indian Journal of Chemical Technology 19:26-31.
(27) Zhiguang Ma, Na Di, Fang Zhang, Peipei Gu, Suwen Liu and Pan Liu (2011). Kinetic and Thermodynamic Studies on the Adsorption of Zn2+ onto Chitosan-aluminium Oxide Composite Material. International Journal of Chemistry 3 (1):18-23.
(28) Nizam M. El-Ashgar, Zeyad J. Yasseen (2009). Complexation and Thermodynamic Studies of Polysiloxane Iminobis (N-Diethylenediamineacetamide) Ligand System with Some Transition Metal Ions. Physical Chemistry an Indian Journal 4(2): 71- 76.
(2) Evangelo Min H, Ebel M, Chaeffer A (2007). Chelate Assistant Phyto Extraction of Heavy Metals from Soil. Effect, Mechanism, Toxicity and Fate of Chelating Agents. Chemosphere 68: 989-1004.
(3) Malarkodi, M, Krishnasany, R., Kumaraperumal, R and Chitedeshwari, T. (2007). Characterization of Heavy Metal Contaminated Soils of Coimbatore District in Tanul Nedu. Journal of Agronomy. 1:147-151.
(4) Durai G and Rajasimman M (2001) Biological Treatment of Tannery Wastewater – A Review. Journal of Environmental Science and Technology 4 (1): 1 -7.
(5) Islam, B I; Musa, A E; Ibrahim, E H; Salma A.A Sharafa and Babiker M. Elfaki (2014) Evaluation and Characterization of Tannery Wastewater. Journal of Forest Products and Industries, 3(3), 141-150.
(6) Muthukkauppan M, and Parthiban P (2018) A Study on The Physicochemical Characteristics of Tannery Effluent Collected from Chennai. International Research Journal of Engineering and Technology (IRJET) 05 (03): 24-28.
(7) Jahan, M. A. A., Akhtar N., Khan, N. M. S., Roy, C. K., Islam, R. and Nurunnabi (2014) Characterization of Tannery Wastewater and Its Treatment by Aquatic Macrophytes and Algae. Bangladesh J. Sci. Ind. Res. 49(4), 233-242.
(8) El-Ashgar, N M (2009) Extraction and Pre-concentration Capacity of Bi-functionalized Diamine –Thiol Polysiloxane immobilized Ligand System towards Some Divalent Cations. Journal of Iran Chem. Soc., 6 (4):823-830.
(9) Issa M. El-Nahhal, Basher A. El-Shetary, Kamal A. R Salib, Nizam M. El- Ashgar, Ahmed M. El- Hashash (2010) Uptake of Divalent Metal Ions ( Cu2+, Ni 2+ and Co2+) by Polysiloxane Immobilized Triamine- Thiol and Thiol-Acetate Ligand System. Analytical Letters 34 (12):2189-2202.
(10) Abdussalam Salhin Mohammad Ali, Norfarhah Abdul Razak; Ismail Ab Rahman (2012) Study on the Preparation of a Sol-Gel Sorbent Based Thiosemicarbazone for Selective Removal of Heavy Metal Ions. World applied sciences journal 16 (8): 1040-1047.
(11) Piotr Grzesiak, Joanna Lukaszyk, Elzbieta Gabala, Joanna Kurczewska, Grzegorz Schroeder (2016) The Influence of Silica Functionalized With Silanes on Migration of Heavy Metals In Soil. Polish Journal of Chemical Technology, 18 (1):51-57.
(12) Akan, J.C., Abdulrahaman, F.I., Ogugbuaja, V.O. and Reuben, K.D. (2009) Study of the Physico-Chemical Pollutants in Kano Industrial Areas, Kano State, Nigeria. J. Applied Sci. 4 (2) 89-102.
(13) Danazumi, S. and Bichi, M.H. (2010) Industrial Pollution and Implication on Source of Challawa River in Kano, Nigeria. Int. Journal of Engineering and Technology IJET-IJENS 10:01.
(14) Shahida Parveen, Ram Bharose and Dharam Singh (2017) Assessment of Physico-Chemical Properties of Tannery Waste Water and Its Impact on Fresh Water Quality Int.J.Curr.Microbiol.App.Sci 6(4): 1879-1887.
(15) Parveen, S., Bharose, R., and Singh, D.(2017). Assessment of physicochemical properties of tannery wastewater and its impact on fresh water quality, Int. J. Curr. Microbiol. Appl. Sci., 6(4), 1879–1887.
(16) Bernard, E. And Jimoh, A. (2013). Adsorption of Pb, Fe, Cu, and Zn from Industrial Electroplating Wastewater by Orange Peel Activated Carbon. International Journal of Engineering and Applied Sciences. 4 (2):95-103.
(17) Senthil Kumar P and Kirthika K. (2009) Equilibrium and Kinetic Study of Adsorption of Nickel from Aqueous Solution onto Bael Tree Leaf Powder. Journal of Engineering Science and Technology 4 (4):351-363.
(18) Horsfall, M. J., Abia, A A. And Spiff, A. I. (2006). Kinetic Studies on the Adsorption of Cd2+, Cu2+ and Zn2+ Ions from Aqueous Solutions by Cassava (Manihotesculenta) Tuber Bark Waste. Journal Bioresource Technology, 97 (35): 283-291.
(19) Brad Busche, Robert Wiacek, Joseph Davidson, View Koonsiripaiboon, Wassana Yantasee, Shane Addleman R, Glen E. Fryxell (2009) Synthesis of Nanoporous Iminodiacetic Acid Sorbents for Binding Transition Metals. Inorganic Chemistry Communications 12:312-315.
(20) El-Nahhal,I.M., El-Ashgar, N. M., A. Abu-Shawish, A., Ahmed, M.A.E., and F. Babonneau, F.(2015). Template synthesis of immobilizedpolysiloxane diamine-thiol tetraacetic acid Biligand system and its application for determination of metal ions, Phosphorus, Sulfur Silicon Relat. Elem., 190(10), 1646–1657.
(21) Mona A. Ahmed, Asmah A. Abu Shaweesh, Nizam M. El-Ashgar, Issa M. El-Nahhal, Mohammed M, Chehimi, Florence Babonneau (2016) Synthesis and Characterization of Immobilized- Polysiloxane Monoamine-Thiol Triacetic Acid and its Diamine and Triamine Derivatives. Journal of Sol Gel Sci Technol 78:660-672.
(22) Bulus H, Ezeh E.C, Shekarri T.B and Pascalina L (2019). Evaluation of Heavy Metal Deposits and distribution in Challawa Industrial Area of Kano Metropolis, Nigeria. Journal of Experimental Research, Vol 7 (1):41-48.
(23) Bulus Habila, Pius Onyeoziri Ukoha, Stanley I. R. Okoduwa, Ahmed Salim, Muazu B. Babangida and Adamu Simon (2020). Synthesis and characterization of an immobilized thiosalicylic–mercaptoethanol biligand system and its application in the detoxification of chromium(III) and iron(III) ions from tannery wastewater New J. Chem., 44, 2321-2327.
(24) Neudachina, L.K. and Lakiza,N.V. (2014) Complexation of transition metal ions on the surface of carboxylated aminopolysiloxanes, Russ. J. Inorg. Chem., 59(6), 632–636.
(25) Parimalam Ramachandran, Raj Vairamuthu and Sivakumar Ponnusamy (2011) Adsorption Isotherms, Kinetics,Thermodynamics and Desorption Studies of Reactive Orange16 on Activated Carbon Derived From Ananas Comosus (L.) Carbon. ARPN Journal of Engineering and Applied Sciences. 6, (11):15-26.
(26) Rajashree Kobiraj; Neha Gupta; Atul Kumar Kuswaha; Chattopadhyaya M. C (2012) Determination of Equilibrium, Kinetics and Thermodynamic Parameters for Adsorption of Brilliant Green Dye from Aqueous Solutions onto Eggshell Powder. Indian Journal of Chemical Technology 19:26-31.
(27) Zhiguang Ma, Na Di, Fang Zhang, Peipei Gu, Suwen Liu and Pan Liu (2011). Kinetic and Thermodynamic Studies on the Adsorption of Zn2+ onto Chitosan-aluminium Oxide Composite Material. International Journal of Chemistry 3 (1):18-23.
(28) Nizam M. El-Ashgar, Zeyad J. Yasseen (2009). Complexation and Thermodynamic Studies of Polysiloxane Iminobis (N-Diethylenediamineacetamide) Ligand System with Some Transition Metal Ions. Physical Chemistry an Indian Journal 4(2): 71- 76.
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Published
2020-10-23
How to Cite
Habila, B. ., Pius O., U. ., Emmanuel C., E. ., Oguejiofo, U. ., John C, A. ., & Moses S, S. . (2020). Synthesis and Characterization of Immobilized Thiolactic Ligand System for the Detoxification of Tannery Wastewater. European Journal of Applied Sciences, 8(5), 18–27. https://doi.org/10.14738/aivp.85.8790
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