Poly (8-Hydroxyquinoline) Properties, Different Methods for Characterization, and New Applications for Different Uses: Review Article

  • Mohamed Shahata Assiut University
Keywords: Keywords: Poly(8-Hydroxyquinoline), Voltammetry, spectra, Immobilization, Aluminum Oxide, Silica gel.


Poly (8–Hydroxyquinoline) (PHQ) has been synthesized by oxidation of the 8–hydroxyquinolate. In addition, Polymeric metal has a great significance in various areas of chemistry. It has several different methods that, used for characterization as FTIR spectroscopy, 1HNMR Spectroscopic, Differential Scanning Calorimetry (DSC), Thermal Gravimetric (TG), Differential Thermal Gravimetric (DTG) have been used. The cathodic stripping voltammetric of the PHQ at the hanging mercury dropping electrode (HMDE) shows a very weak signal at negatively charged electrode potential.   Spectro analytical Sensitivity for PHQ coordination polymers with different metal ions have been calculated. Potentiometric Studies of a Polymeric and Coordination Polymeric Form of 8- Hydroxyquinoline. Cation exchange properties have been researched by spectrophotometric technique. Immobilization of Monomeric, Polymeric and Polymeric Chelates Forms of (8-Hydroxyquinoline) Matrix incorporated in Aluminum Oxide used to be studied. Also, Immobilization of Monomeric, Polymeric and Polymeric Chelates Forms of (8-Hydroxyquinoline) Matrix into Silica Gel has been carried out.  Various applications for previous studies in different areas can be used as: Analytical Application, Preconcentration of some metal Ions, and get a patent about Poly(8-Hydroxyquinoline) immobilized on some substance as risen for removal of metal ion. 


(1) Chin,T. K.; Show, A. C.; Hwang, G. W.; Hsiao, H. K. "Field-effect transistor with the water-soluble self-acid-doped polyaniline thin films as semiconductor". Synthetic Metals. 1998, 93 (331), 155 - 160.

(2) Ogura, K., Shiigi, H.; Nakayma, M.; Fujii, A.; "Thermogravimetric / Mass and Infrared Spectroscopic Properties and Humidity Sensitivity of Polyaniline Derivatives/Polyvinyl Alcohol Composites". Journal of The Electrochemical Society. 1998, 145 (10), 5331.

(3) Wessling, B. "Dispersion as the link between basic research and commercial applications of conductive polymers (polyaniline)". Synthetic Metals. 1998, 93(2), 143 -154.

(4) Yong, C.; George M. T.; Paul S.; Heeger, A.J. "Solution‐cast films of polyaniline: Optical‐quality transparent electrodes". Appl. Phys. Lett. 1992, 60, 2711.

(5) Tsumura, A.; Koezuka, H.; Ando, T. "Macromolecular electronic device: Field‐effect transistor with a polythiophene thin film". Appl. Phys. Lett. 1996, 49, 1210.

(6) Burroughes, J. H.; Bradley, D. C.; Brown, A. R.; Marks, R. N.; Mackay, K.; Friend, R. H.; Burn, P. L.; Holmes, A. B. "Light-emitting diodes based on conjugated polymers". Nature, 1990, 347 (6293) 539-541.

(7) Nagaoka, T.; Nakao, H.; Suyama, T.; Ogura, K.; Oyama, M.; Okazaki, S. "Electrochemical Characterization of Soluble Conducting Polymers as Ion Exchangers". Analytical Chemistry, 1997, 69 (6), 1030-1037.

(8) Chen, Z.; Okimoto, A.; Kiyonaga, T.; Nagaoka, T. "Preparation of Soluble Polypyrrole Composites and Their Uptake Properties for Anionic Compounds". Analytical Chemistry, 1999, 71(9), 1834-1839.

(9) Nagaoka, T.; Nakao, H.; Ougra, K. "Preparation of Soluble Polyaniline and Its Voltammetric Behavior for lon Exchange". Analytical Sciences, 1996, 12(1), 119.

(10) Hepel, M. "Composite poly pyrrole films switchable between the anion- and cation-exchanger states". J. Electrochem Acta, 1996, 41, 63-76.

(11) Murray, R.W. "Electroanalytical chemistry", vol. 13 (A. J. Bard, ed.) (Marcel Dekker, New York, 1984, pp. 191–368.

(12) Murray, R.W. "Polymer Modification of Electrodes". Annu. Rev. Mater. Sci., 1949, 14, pp. 145–169.

(13) Hillman, A. R. "Electrochemical science and Technology of polymers". vol. 1 (R. G. Linford, ed) (Elsevier, Amsterdam), 1987, 241, pp 103 – 239.

(14) Hamnett, A.; Hillman, R. "A study of the electrochemical growth and optical properties of polymeric thionine films on platinum using ellipsometry". Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1987, 233(1–2), 125-146.

(15) (a) Abruña, H.D. "Coordination chemistry in two dimensions: chemically modified electrodes". coord. Ch. Re.,1988, 86, 135-139.; (b) Abruna, H.D. "Electro responsive molecular and polymeric systems". vol. 1 (T. A. Skotheim, ed.), Marcel Dekker, New York,1988, pp. 98–160.

(16) Smyrl, W.H.; Lien, M. "Applications of electroactive polymers". (B. Scrosati, ed.) (Chapman and Hall, London),1993, pp. 29–74.

(17) Kaner, R.B. "Electrochemical science and technology of polymers". vol. 2 (R. G. Linford, ed.) (Elsevier, London),1990, pp. 97–147.

(18) Pethrick, R.A. "Electrochemical science and technology of polymers". vol. 2 (R. G. Linford, ed.) (Elsevier, London),1990, pp. 49 – 96.

(19) Lyons, M.E.G. "Electrochemistry novel interfaces and macromolecular electroactive systems". Annu. Rep. Prog. Chem., Sect. C: Phys. Chem.,1990, 87, 119-171.

(20) Oyama, N.; Ohsaka, T. "Molecular design of electrode surfaces". (R. W. Murray, ed.) techniques of chemistry series, vol. 22, (Wiley interscience, New York) 1992.

(21) Lyons, M.E.G. "Electroactive polymer electrochemistry". part 1, Fundamentals, plenum press-New York and London, 1994.

(22) Saleh, N.A.; Suliman, F.O.; Zaid R.A. "8-Hydroxyquinoline and its Derivatives: Synthesis and Applications". Research and Reviews: Journal of Chemistry, RRJC, 2014, 3 (1), 1-10.

(23) Angelova, M.N.; Rashkov, N. "Metal ion complex formation of poly(oxyethylene) with 5-chloro-8-quinolinoxyl end-groups". I. Eur. Polym. J.,1995, 31, 741-748.

(24) Monolova, M.I.; Rashkov, M. "Preparation and metal ion complexing ability of polyethers with 8-hydroxy-5-quinolinyl end-groups". I .Eur. Polym. J.,1998, 34, 1133-1141.

(25) Monolova, B.M.; Rashkov, N. "Poly(ϵ-caprolactone)s with 5-nitro and 5-chloro-8-quinolinoxyl end-groups". I. Eur. Polym. J.,1994, 30, 1179-1185.

(26) Ebraheem K. A. K.; Mubark M. S.; Yassien Z.J. K. "Chelation properties of poly(8-Hydroxyquinline 5,7-diylmethylene) towards some trivalent lanthanide metal ions". Solvent Extr. Ion Exch., 1998, 16, 637-649.

(27) Bellman J.L. "The infra-red spectra of complex molecules". Chapman and Hall, London,1975, pp.131-132.

(28) Adel Z.E.; Ahmed B. A.; Amira, M.H. "Polymer complexes. XXIX. Novel polymer complexes prepared from poly(1-acrylamido-2(2-pyridyl) ethane". Polym. Deg. Stab., 1995, 48, 45-53.

(29) Binod, B.D.; Braj, B.L.; Swaminathan S.; Pradeep K.D. "Synthesis of Catalytically Active Polymer-Bound Transition Metal Complexes for Selective Epoxidation of Olefins". Macromolecul,1994, 27, 1291–1296.

(30) Kamble, K.J.; Patkar, D.N. "Synthesis and characterization of oxime resin of poly(4‐viny1, 2′‐carboxybenzophenone) and its metal". polychelates J. Appl. Polym. Sci.,1995, 56, 1519-1521.

(31) Newton, L.; Filho, D. "Adsorption and structure of copper(II) complexes on a silica gel surface chemically modified with 2-aminothiazole". polyhedron,1999, 18, 2241-2247.

(32) Kobayashi, S.; Tokunoh, M.; Saegusa, T.; Mashio, F. "Poly(allylamine) chelating properties and resins for uranium recovery from seawater". Macromolecul.,1985, 18 (12), 2357–2361.

(33) Soessel, S.J.; Stille, J.K. "Polyquinoline-supported ruthenium complex for the photochemical reduction of water". Macromolecul.,1992, 25 (6), 1832–1837.

(34) Nonaka, T.; Umeura, Y.; Enishi, K.; Kurihara, S. "Antibacterial activity of resin‐containing triethylenetetramine side chains and/or thiol groups–metal complexes". J. Appl. Polym. Sci.,1996, 62, 1651-1659.

(35) Alexo, L.M.; Sousa, M.F.B.; Godinho, O.E.S.; Oliveraneto, G.; Gashikem, Y. "Development of a chemically modified electrode based on carbon paste and functionalized silica gel for preconcentration and voltammetric determination of mercury(II)". Anal. Chim. Acta,1993, 271, 143-148.

(36) Lorencetti, L.L.; Gushikem, Y.; Kubota, L.T.; Neto, G.O.; Fernandes, J.R. "Potentiometric Study Using Chemically Modified Silica Gel with Pyridinium as Membrane". Microchem. Acta,1995, 117, 239-244.

(37) Sousa, M.F.; Bertazzoli, R. "Preconcentration and Voltammetric Determination of Mercury(II) at a Chemically Modified Glassy Carbon Electrode". Anal. Chem.,1996, 68 (7), 1258-1261.

(38) Tsysin, G.I.; Zolotov, Y.A. "Dynamic Sorption Preconcentration of Platinum Metals". Mendeleev Communications,1995, 5(3), 111-112.

(39) Newton, L.; Filho, D. "Adsorption of Cu(II) and Co(II) complexes on a silica gel surface chemically modified with 2-mercaptoimidazole". Microchimica Acta,1999, 130, 233–240.

(40) Thomsen, D.L.; Phely-Bobin, T.; Opoulos, F.P. "Zinc-Bisquinoline Coordination Assemblies of High Refractive Index and Film Uniformity". J. Am. Chem. Soc.,1998, 120(24), 6177– 6178.

(41) Young, R.G. “ Introduction to polymers ”. (Chapman and hall, London), 1981.

(42) Seddique, M.A.; Shahata, M.M.; Kamal, M.M. "Spectrophotometric Studies of the Coordination Polymer Based on Poly (8–Hydroxyquinoline) Matrix". Journal of Inorganic and Organometalic Polymer ,2003, 13(3), 171-

(43) Tümer, M.; Erdogan, B.; Köksal, H.; Serin, S.; Nutku, M.Y. "Preparation, Spectroscopic Characterisation and Thermal Analyses Studies of the Cu(II), Pd(II) and Vo(IV) Complexes of Some Schiff Base Ligands". Synth. React. Inorg. Met. Org. Chem.,1998, 28(4), 529-542.

(44) Kaliyappan, T.; Raman, A.; Kannan, P. "Studies on poly(8-Acryloyloxy-quinoline) and its metal complexing ability in aqueous medium". Macromol Sci. Part A, Pure Appl. Chem.,1999, 36, 517-530.

(45) Sung, S.I.; Byun, S.W. "Preparation and properties of transparent and conducting nylon 6‐based composite films". J. Appl. Polym. Sci.,1994, 51, 1221-1229.

(46) Mostafa, M.K.; Seddique, M.A.; Mohamed, M.S.; Temerk, Y.M. "Differential Pulse Polarographic of Poly (8–Hydroxyquinoline) Matrix". Anal. and Bioanal. Chem.,2002, 372, 843 – 848.

(47) Ghosh,P.; Siddhanta, S.K.; Chakrabarti, A. "Characterization of poly(vinyl pyrrolidone) modified polyaniline prepared in stable aqueous medium". Eur. Polym. J.,1999, 35, 699-710.

(48) Seddique, M.A.; Bahaa, M.Z. "Thermal degradation studies of the reduced and oxidized poly(o-toluidine) matrix". J. Anal. Appl. Pyrolysis, 2003, 70 (2), 277-289.

(49) Temerk, Y.M.; Valenta, P. "Electrochemical behavior of mono- and oligonucleotides: Part V. Voltammetric studies on the adsorption stages and interfacial orientations of cytidine at charged interfaces". J. Electroanal.

Chem.,1978, 93, 57-67.

(50) Temerk, Y.M.; Valenta, P.; Nurnberg, H.W. "Electrochemical behavior of mono-and oligonucleotides and the corresponding nucleosides: Part VI. Comparative voltammetric study on the adsorption of 1-β-D-

arabinofuranosylcytosine and 1-β-D-ribofuranosylcytosine at charged interfaces". J. Electroanal. Chem.,1979, 100,


(51) Temerk, Y.M. "Studies on the adsorption and the association of cytidine sulphate at the dropping mercury electrode with phase-sensitive ac-polarography". Can. J. Chem, 1979, 57(10), 1136-1140.

(52) Temerk, Y.M.; Valenta, P.; Nurnberg, H.W. "Electrochemical behaviour of mono- and oligonucleotides: Part VII. Comparative studies on the adsorption of cytidine at the mercury-aqueous solution interface by pulse polarography and ac polarography". J. Electroanal. Chem.,1980, 109, 289-300.

(53) Temerk, Y.M.; Kamal, M.M.; Ahmed, M.E.; Ibrahim, M. "Differential pulse polarographic determination of some nucleic acid components". Bioelectrochemistry and Bioenergetics,1983, 11(4-6), 449-456.

(54) Temerk, Y.M.; Valenta, P.; Nurenberg, H.W. "Voltammetric studies on the interfacial behaviour of mono-, di- and triphosphate of cytidine". J. Bioelectro Chem. Bioenerg.,1980, 7, 705-722.

(55) James, A.M. "Polarography and other voltammetric methods". London, 1987, p. 167.

(56) Stock, J.T. "The polarography of quinoline derivatives. Part II. The reduction of 8-hydroxyquinoline at the dropping-mercury cathode". J. Chem. Soc.,1949, 586-589.

(57) Philips J. P.; Fernando, Q. "Polarography of 8-Quinolinol-5-sulfonic Acid". J. Am. Chem. Soc.,1952, 74 (17), 4459-4460.

(58) Gupta S. L.; Rashavan P. S. "Polarography of 7-nitro-8-hydroxyquinoline-5-sulphonic acid". Electrochem. Acta,1971, 16, 1613-1618.

(59) Stock, J.T. "The polarography of quinoline derivatives. Part III. The reduction of quinoline-8-carboxylic acid at the dropping-mercury cathode". J. Chem. Soc.,1949, 763-766.

(60) Stock, J.T. "The reduction of quinaldinic acid at the dropping-mercury cathode". J. Chem. Soc.,1944, 427-430.

(61) Stock, J.T.; Williams, T.R.; Pinchin, F.J. "The polarography of quinoline derivatives. Part VII. The reduction waves of quinoline-3-, -5-, -6-, and -7-carboxylic acids". J. Chem. Soc.,1960, 3221-3225.

(62) Turner, W.R.; Stock, J.T. "The polarography of quinoline derivatives. Part VIII. The reduction waves of certain 8-substituted quinaldines and quinaldinic acids". J. Chem. Soc.,1965, 1506-1511.

(63) Bosserman, P.; Sawyer, D.T.; Albert, L. "Differential pulse polarographic determination of molybdenum at parts-per-billion levels". Anal. Chem, 1978, 50 (9), 1300–1303.

(64) Bhowal S. K., Umland, F. "Polarographic determination of molybdenum after extraction of its N-benzoyl-N-phenylhydroxylamine complex". Fersenius Anal Chem.,1976, 282(3), 197-200.

(65) Song, M.; Ma, H.; Huang, Y.; Liang, S. "Determination of poly(vinyl alcohol) by adsorptive stripping voltammetry based on its copper(II) complex". Anal Chim. Acta,1997, 338, 103-108.

(66) Temerk, Y.M.; Aly, A.A.M.; Kamal, M.M.; Ibrahim, S.A. "Coordination properties of Salicylidene Salicyloyl Hydrazone and related ligands with copper(II) sulphate, nitrate and acetate". J. Prakt. Chem,1986, 328, 285 – 290.

(67) Kamal M. M.; Aly A. M.; El-Meligy, M. S.; El-Said, A. I. "Studies on Some Metal Chelates of 8-Hydroxy-Quinoline-5-Sulphonylhydrazide". Synth React Inorg Chem.,1989, 19, 557-569.

(68) Kamal, M.M.; Temerk, Y.M.; Ahmed, Z.A.; Ahmed, G.A. "Differential pulse polarographic determination of some substituted benzylidene acethyrazones". Analusis,1989, 17, 532-539.

(69) Issa, I.M.; Temerk, Y.M.; Abu Zhuri, A.Z.; El-Meligy, M.S.; Kamal, M.M. "Studies on the reaction of salicylidenebenzoic-hydrazide (SBH) with Ce3+, Th4+ and UO2 2+". Monatshefte für Chemie / Chemical Monthly.1980, 111, 1151–1158.

(70) Seddique, M.A.; Patil, R.C.; Nakayama, M.; Ogura, K. "Characterization of picric-acid-doped poly(o-toluidine) and the picric-acid-doped poly(o-toluidine)-induced conductive composite of acrylonitrile–butadiene–styrene". Synth Met.,2000, 114, 155-160.

(71) Patil, R.C.; Seddique, M.A.; Ogura, K. "Preparation and Characterization of Highly Transparent Conducting Composites Consisting of Acid-Doped Poly(o-toluidine) and Poly(methyl methacrylate)". Polymer Journal, 2000, 32, 466–470.

(72) Nagaoka,T.; Seddique, M.A.; Ogura, K. "Electroactivity of Poly pyrrole Colloids Enhanced by Quinone Mediation". J. Electrochem.1999, Soc., 146, 3378.

(73) Patil, R. C.; Ahmed S. M.; Shiigi, H.; Nakayama, M.; Ogura K. "Investigation of some physicochemical properties of camphor sulfonic acid (CSA)–doped poly(o ‐anisidine) (PoAN) and CSA‐doped PoAN/ABS composites". J. Polym. Sci. Part A: polym. Chem.,1999, 37, 4596-4604.

(74) Ahmed S. M., Nagaoka T., Ogura K. (1998). "Electrochemical and Spectro electrochemical Characterization of Some Poly pyrrole/Anthraquinone Sulfonate Films". Anal.1998, Sci., 14(3), 535.

(75) Luther, G.W.; Stephen, M.T.; Rickard, D. "Determination of stability constants for metal–ligand complexes using the voltammetric oxidation wave of the anion/ligand and the De Ford and Hume formalism". Talanta, 2000, 51, 11–20.

(76) Carmen, H: Berbel, F.; Dı́az-Cruz, J.M.; Ariño, C.; Esteban, M. "Voltammetric metal speciation in mixtures of inert and labile macromolecular complexes at any ligand-to-metal ratio: differential pulse polarographic study of the Zn(II)–nitrilotriacetate–polymethacrylate system". Journal of Electroanalytical Chemistry, 2000, 462(218), 157-

(77) Shuman, M.S.; Woodward, G.P. "Chemical constants of metal complexes from a complexometric titration followed with anodic stripping voltammetry". Anal. Chem.,1973, 45(12), 2032–2035.

(78) Shuman, M.S.; Woodward, G.P. "Stability constants of copper-organic chelates in aquatic samples". Environ. Sci. Technol., 1977, 11(8), 809–813.

(79) Hage, D.S.; Walters, R.R.; Hethcote, H.W. "Split-peak affinity chromatographic studies of the immobilization-dependent adsorption kinetics of protein A". Anal. Chem.,1986, 58(2), 274–279.

(80) Edward E. Menden, Victor J. Elia, Leslie W. Michael, and Harold G. Petering, H.G. "Distribution of cadmium and nickel of tobacco during cigarette smoking". Environ. Sci. Technol.,1972, 6(9), 830–832.

(81) Mussalo-Ranhamoa, H.; Salmela, S.S.; Leppanen, A.; Pysalo, H. "Cigarettes as a Source of Some Trace and Heavy Metals and Pesticides in Man". Arch. Environ. Health,1986, 41, 49-55.

(82) Moore, J.W.; Ramamoothy, S. "Heavy metals in natural waters" (Eds,) Spring–verag, New York, 1984.

(83) Cappaccio, R. "Electroless Plating, Fundamentals and Applications" (Eds; G. O. Mallory, J. B. Hajdu), AESF socity, Orland, FL,1991, pp. 519–528.

(84) Kunces, D. "Products Finishing, December, Hope for the Best But be Prepared for the Worst", 1987, 85.

(85) Suslik, S. "Industrial Finishing, Suslik, Industrial Finishing, Applications of Ion Exchange: Pollution Abatement”, 1983, 6, p. 16.

(86) Plank, C.; Mechtler, K.; Szoka, F.C.; Wagner, E. "Activation of the Complement System by Synthetic DNA Complexes: A Potential Barrier for Intravenous Gene Delivery". Human gene therapy, 1996, 7(12), 1437–1446.

(87) Verckyusse, A. "Hazardous metals in Human Texicology", Elsevier, Amestrdam, 1984.

(88) Tznzawa, H.; Mori, Y.; Harumiya, N.; Miyama, H.; Hori, M.; Ohshima, N.; Idezuki, Y. "Preparation and evaluation of a new athrombogenic heparinized hydrophilic polymer for use in cardiovascular system". Trans.

Am. Soc. Artif. Intern. Organs.1973, 19, 188- 194.

(89) Sato, T.; Kamachi, M.; Mizusaki, M.; Yoda, K.; Morishima, Y. "Binding of Lysozyme to Unimolecular Micelles Formed from Hydrophobically-Modified Polyelectrolytes". Macromolecul.1998, 31(20), 6871-6877.

(90) Wei, C.; German, S.; Basak, S.; Rajeshwar, K. "Reduction of hexavalent chromium in aqueous solutions by poly pyrrole". Electrochem. Soci.1993, 140, 160.

(91) Shahata, M.M.; Seddique, M.A.; Kamal, M.M. "Cathodic Stripping Differential Pulse Voltammetric Determination of Poly(8–Hydroxyquinoline) Matrix". IJPAC-International Journal of Pure and Applied Chemistry, 2013, 8(3), 209-216.

(92) Zhang, H.; Wollast, R.; Vire, J.C.; Patriarche, G.j. "Simultaneous determination of cobalt and nickel in sea water by adsorptive cathodic stripping square-wave voltammetry". Analyst,1989, 114, 1597-1602.

(93) Zhang, J.Z.; Millero, F.J. "Investigation of metal sulfide complexes in sea water using cathodic stripping square wave voltammetry". Anal. Chim. Acta,1994, 284, 497-504.

(94) Viltchinskaia, E.A.; Zeigman, D.M.; Garcia, D.M.; Santos, P.F. "The Effect of Organic Substances and Electrochemical Elimination of it for Cathodic Stripping Voltammetric Determination of Manganese (II) in Natural Waters". Anal. Lett.1995, 28, 1845-1863.

(95) Temerk, Y.M.; Kamal, M.M.; Ahmed, Z.A.; Ahmed, M.E.; Ibrahim, M.S. "Adsorptive stripping analysis of thiocytosine at the static mercury electrode surface". Fresenius' Journal of Analytical Chemistry,1992, 342, 601–

(96) Y. M. Temerk, Z. A. Ahmed, M. E. Ahmed, M. S. Ibrahim and M. M. Kamal. (1993). Cathodic adsorptive stripping voltammetry of 6-thiopurine in absence and presence of some metal ions. Fresenius J. Anal. Chem.1993, 345, 733–736.

(97) Haaland, D.M.; Thomas, E.V. "Partial least-squares methods for spectral analyses, Relation to other quantitative calibration methods and the extraction of qualitative information". Anal. Chem.1988, 60(11), 1193–1202.

(98) Carey, W.P.; Beebe, K.R.; Kowalski, B.R. "Multicomponent analysis using an array of piezoelectric crystal sensors". Anal. Chem., 1987, 59(11), 1529–1534.

(99) Wold, S.; Esbensen, K.; Geladi, P. Principal component analysis. Chemometrics and Intelligent Laboratory Systems,1987, 2, (1–3), 37-52.

(100) Hagis, L.G.; Howell, J.A. "Ultraviolet and light absorption spectrometry". Anal. Chem.1992, 64 (12), 66–79.

(101) Howel, J.A.; Hargis, L.G. "Ultraviolet and Light Absorption Spectrometry". Anal. Chem., 1994, 66(12), 445–461.

(102) Bernard, M.; Goff, A.H.; Bich, V.T.; Zeng, W. "Study by optical multichannel analysis of the electrochromic phenomena in polyaniline doped with camphor sulfonic acid". Synth. Met.1996, 81,215-219.

(103) Bernard, M.C.; Goff, A.H.; Zeng, W. "Characterization and stability tests of an all solid state electrochromic cell using polyaniline". Synthetic Metals, 1997, 85(1–3), 1347-1348.

(104) Taneja, A.D.; Srivastava, K.P. "A spectrophotometric determination of the stability constants of the iron(III)-acetoacetanilide chelate". Journal of Inorganic and Nuclear Chemistry,1971, 33(8), 2678-2680.

(105) Khopkar, S.M. "Basic concepts of Analytical Chemistry”. Wiely, 1988, pp.188–191.

(106) Ghosh, P.; Siddhanta, S.K. "Studies on stable aqueous poly(o ‐toluidine) prepared with the use of a water soluble support polymer, polyacrylamide". J. Polym. Sci. part A: Polym. Chem.1999, 37, 3243-3256.

(107) Legget, D.J (ed.), "Computational methods for the determination of formation constants". Plenum Press, New York, 1985.

(108) Martell, A.E.; Motekaitis, R.J. VCH, New York, 1988.

(109) Douheret, G. "Medium effects in aqueous organic solvents. Influence of solute on transfer parameters". Journal of Electroanalytical Chemistry and Interfacial Electrochemistry,1975, 61(225), 228-232.

(110) Shahata, M.M. "Determination of the Formation Constants of Some Metal Ions Coordinated with poly (8–Hydroxyquinoline)". International Journal of Advanced Research, 2014, 2(6), 96-109.

(111) Shahata, M.M. "Formation Constants and Partial Formation Constants of Some Metal Ions Coordinated with 8–Hydroxyquinoline by Potentiometric Titration". American Journal of Chemistry and Application, 2015, 2(3), 37-46.

(112) Liu, J.; Wang, X.; Chen, G.; Gan, N.; Bi, S. "Speciation of aluminum (III) in natural waters using differential pulse voltammetry with a Pyrocatechol Violet-modified electrode". Analyst, 2001,126, 1404-1408.

(113) Song, M.; Ma, H.; Huang, Y.; Liang, S. "Determination of poly(vinyl alcohol) by adsorptive stripping voltammetry based on its copper(II) complex". Anal. Chim. Acta, 1997, 338, 103-108.

(114) Erdoğdu, G.; Karagözler, A.E. "Investigation and comparison of the electrochemical behavior of some organic and biological molecules at various conducting polymer electrodes". Talanta,1997, 44, 2011-2018.

(115) Sprague , J.S.; Tai, J.C.; Yuh, Y.; Allinger, N.L. "The MMP2 calculational method". Comput. Chem.1987, 8, 581-603.

(116) Irving, H.; Rossotti, H.S. "Methods for computing successive stability constants from experimental formation curves". J. Chem. Soc.1953, 3397 – 3405.

(117) Irving, H.M.; Rossotti, H.S. "The calculation of formation curves of metal complexes from pH titration curves in mixed solvents". J. Chem. Soc.1954, 2904-2910.

(118) De Roberties, A.; De Stefano, C.; Gianguzza, A.; Sammartano, S. "Binding of polyanions by biogenic amines III, Formation and stability of protonated spermidine and spermine complexes with carboxylic ligands". Talanta, 1999, 48, 119–126,

(119) Kamal, M.M.; Al-Syed, A.Y.; Seddique, M.A.; Shahata, M.M. "Cation exchange mobility on Poly(8-hydroxyquinoline) matrix". International Journal of Inorganic and Organometalic Polymer and material, 2009, 19(4), 501-506.

(120) Ahmed, S.A. "Chromaticity of poly(o-toluidine) matrix enhanced by anion-exchange mechanism". Chemical Papers, 2007, 61, 464–471.

(121) Liu, Y.; Liang, P.; Guo, L. "Nanometer titanium dioxide immobilized on silica gel as sorbent for preconcentration of metal ions prior to their determination by inductively coupled plasma atomic emission spectrometry". Talanta, 2005, 68, 25-30.

(122) Hadjiivanov, K.; Klissurski, D.; Kantcheva, M.; Davydov, A. "State and localization of cobalt, nickel and copper ions adsorbed on titania (anatase)". J. Chem. Soc. Faraday Trans., 1991,87, 907-911.

(123) Vassileva, E.; Varimezova, B.; Hadjiivanov, K. "Column solid-phase extraction of heavy metal ions on a high surface area CeO2 as a preconcentration method for trace determination". Anal. Chim. Acta, 1996, 336, 141-150.

(124) Shabani, M.H.; Dadfarnia, S.; Dehghan, K. "Preconcentration and determination of cobalt by chelating microcolumns and flow injection atomic spectrometry". Talanta, 2003, 59, 719-725.

(125) Gang, C.; Cheng, J.Z.; Tian Y.P.; Bin, H. "Preparation of High-Specific-Surface-Area Nanometer-sized Alumina by Sol-Gel Method and Study on Adsorption Behaviors of Transition Metal Ions on the Alumina Powder with ICP-AES". Acta Chimica Sinica, 2003, 61 (1), 100-103.

(126) Cui, Y.; Chang, X.; Zhu, X.; Jiang, N.; Lian, N. "Nanometer SiO2 modified with 5-sulfosalicylic acid as selective solid-phase extractant for Fe(III) determination by ICP-AES from biological and natural water samples". Microchem. J, 2007, 86, 23-28.

(127) Hashemi, P.; Bagheri, S.; Fat’hi, M.R. "Factorial design for optimization of experimental variables in preconcentration of copper by a chromotropic acid loaded Q-Sepharose adsorbent". Talnata, 2005, 68, 72-78.

(128) Tiwari, P.K.; Singh, A.K. "Preconcentration of lead with Amberlite XAD-2 and Amberlite XAD-7 based chelating resins for its determination by flame atomic absorption spectrometry". Talanta, 2002, 56, 735-744.

(129) Ramesh, A.; Devi, B.A.; Hasegawa, H.; Maki, T.; Kazumasa, U. "Nanometer-sized alumina coated with chromotropic acid as solid phase metal extractant from environmental samples and determination by inductively coupled plasma atomic emission spectrometry". Microchemical Journal, 2007, 86, 124-130.

(130) Chen, C.H.; Shi, J. "Metal chelates as emitting materials for organic electroluminescence". Coordin. Chem. Rev, 1998, 171, 161-174.

(131) Tao, X.T.; Suzuki, H.; Wada, T.; Miyata, S.; Sasabe, H. "Highly Efficient Blue Electroluminescence of Lithium Tetra-(2-methyl-8-hydroxy-quinolinato) Boron". J. Am. Chem. Soc., 1999,121(40), 9447–9448.

(132) Leung, L.M.; Lo, W.Y.; So, S.K.; Lee, K.M.; Choi, W.K. "A High-Efficiency Blue Emitter for Small Molecule-Based Organic Light-Emitting Diode". J. Am. Chem. Soc., 2000, 122(23), 5640–5641.

(133) Meyers, A. "Doctoral Thesis, Georgia Institute of Technology", December 2004.

(134) Tang, C.W.; Van Slyke, S.A. "Organic electroluminescent diodes". Appl. Phys. Lett., 1987, 51, 913.

(135) Halls, M.D.; Schlegel, H.B. "Molecular Orbital Study of the First Excited State of the OLED Material Tris(8-hydroxyquinoline) aluminum(III)". Chemistry of Materials, 2001, 13(8), 2632-2640.

(136) Curioni, A.; Boero, M.; Andreoni, W.; Curioni, A.; Boero, M.; Andreoni, W. "Alq3: ab initio calculations of its structural and electronic properties in neutral and charged states". Chem. Phys. Lett., 1998, 294, 263-271.

(137) Brinkmann, M.; Gadret, G.; Muccini, M.; Taliani, C.; Masciocchi, N.; Sironi, A. "Different Crystalline Polymorphs and Amorphous Thin Films of mer-Tris(8-hydroxyquinoline) aluminum(III)". J.Am. Chem. Soc., 2000,

(21), 5147–5157.

(138) Sapochak, L.S.; Benincasa, F.E.; Schofield, R.S.; Baker, J.L.; Riccio, K.C.; Fogarty, D.; Kohlmann, H.; Ferris, K.F.; Burrows, P.E. "Electroluminescent Zinc(II) Bis(8-hydroxyquinoline): Structural Effects on Electronic States and Device Performance". J. Am. Chem. Soc., 2002, 124(21), 6119–6125.

(139) M. Ghedini, M,; LaDeda, M.; Aiello, I.; Grisolia, A. "Synthesis and photophysical characterisation of soluble photoluminescent metal complexes with substituted 8-hydroxyquinolines". Synthetic Met., 2003, 138, 189-192.

(140) Francisco, N.; Ricardo, V. "Ab initio study of luminescent substituted 8-hydroxyquinoline metal complexes with application in organic light emitting diodes‏". J. Mol. Struct. Chem., 2008, 850(1-3), 127-134.

(141) Zorba, S.; Gao, Y. "Feasibility of static induction transistor with organic semiconductors". Appl. Phys. Lett., 2005, 86, 193508.

(142) Yi, M.; Yu, S.; Ma, D.; Feng, C.; Zhang, T.; Meruvia, M.S.; Hümmelgen, I.V. "High current density tris(8-hydroxyquinoline) aluminum-based hybrid transistor in vertical architecture". Journal of Applied Physics., 2006, 99, 106102.

(143) Meruvia, M.S.; Hu¨mmelgen, I.A. "Hybrid Molecular/Inorganic Semiconductor Transistors in Vertical Architectures". Adv. Funct. Mater., 2006, 16, 459-467.

(144) Yi, M.; Yu, S.; Feng, C.; Zhang, T.; Ma, D.; Meruvia, M.S.; Hu¨mmelgen, I.A. "High gain in hybrid transistors with vanadium oxide/tris(8-hydroxyquinoline) aluminum emitter". Organic Electronics., 2007, 8, 311-316.

(145) Uthirakumar, P.; Suh, E.; Hong, C. "Effect of zinc oxide incorporation on the morphology of tris(8-hydroxyquinoline) aluminum/zinc oxide hybrid nanomaterials". Thin Solid Films., 2008, 516, 7299-7305.

(146) Yamaguchi, I.; Iijima, T.; Yamamoto, T. "Synthesis and reactivity of Al(Et)q′2 (q′=2-methyl-8-quinolinolato) and crystal structures of [Al(Et)2q]2 and Alq′2q (q=8-quinolinolato)". J. Organomet. Chem., 2002, 654, 229-232.

(147) Yamamoto, T.; Iijima, T. "Fluxional behavior of Al(Et)(q′)2 (q′=2-methyl-8-quinolinolato) studied by temperature dependent 1H NMR spectroscopy". J. Organomet. Chem., 2004, 689, 2421-2424.

(148) Amini, M.M.; Sharbatdaran, M.; Mirzaee, M.; Mirzaei, P. "Synthesis, structure and luminescence study of a binuclear aluminium complex: A novel structure containing six coordinated aluminium atoms in two distinct coordination geometries". Polyhedron, 2006, 25, 3231-3237.

(149) Kamal, M.M.; El- Sayed, A.Y.; Seddique, M.A.; Omran, A.A.; Shahata, M.M. "Pre-concentration of Some Heavy Metal Ions with AlO-HQ and AlO-PHQ and their studies by FTIR and Spectroscopy". Arabian Journal of Chemistry, 2015, 8, 442-449.

(150) Jal, P.K.; Patel, S.; Mishra, B.K. "Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions". Talanta, 2004, 62, 1005-1028.

(151) Shtokalo, M.I.; Kostenko, E.E.; Kolomiets, L.L. "Igor ’Vladimirovich Pyatnitsky, Well-Known Ukrainian Analyst". Journal of Analytical Chemistry, 2005, 60(2), 189-190.

(152) Glad, M.J.; Ohlson, S.A.; Hansson, L.H.; Mansson, M.O.; Larsson, P.O.; Mosbach, K.H. "US Patent" 4, 407, 1983.

(153) Jal, P.K.; Sudarshan, M.; Saha, A.; Patel, S.; Mishra, B.K. "Synthesis and characterization of nanosilica prepared by precipitation method". Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004, 240, 173-178

(154) Vanderheyden, E.; Vansant, E.F.; Philip, P.J. "FFIR-PAS Analysis of Silica Gel Modified with Amines for the Treatment of Natural Gases Contaminated with Sulphur Compounds". Microchim. Acta., 1988, 2, 163-166.

(155) Colli, M.; Girony, A.; Molina, V.; Marchetti, R.; D’Eril, M.G.; Lucarelli, C. "Improved HPLC methodology in occupational exposure studies on formaldehyde". Chromatographia, 1991, 32, 113-115.

(156) Ayadim, M.; Soumillion, J.P. "Photosensitizers covalently anchored to the silica surface: Modulation of the excited state efficiency through electron transfer from the linking arm or from the surface". Tetrahedron Lett., 1995, 36, 4615-4618.

(157) Péré, E.; Cardy, H.; Cairon, O.; Simon, M.; Lacombe, S. "Quantitative assessment of organic compounds adsorbed on silica gel by FTIR and UV–VIS spectroscopies: the contribution of diffuse reflectance spectroscopy". Vib. Spectrosc., 2001, 25, 163-175.

(158) Zolotov, Y.A.; Morosanova, T.M.; Dmitrienko, S.G. "Sorption preconcentration of trace components for chemical analysis". Uspekhi khimii (Advances in Chemistry), 2005, 74(1):41-66.

(159) Mahmoud, M.E. "Comparison of metal sorption properties of three silica gel phases—physically adsorbed and chemically immobilized- 1-aminoanthraquinone". Anal. Lett., 2002, 35, 1251-1267.

(160) Kim, J.; Chah, S.; Yi, J. "Preparation of modified silica for heavy metal removal". Kor. J. Chem. Eng., 2000, 17, 118–121.

(161) Chah, S.; Kim, J. S.; Yi, J. "Separation of Zinc Ions from Aqueous Solutions using Modified Silica Impregnated with CYANEX 272". Separ.Sci. Technol., 2002,37, 701.

(162) Thom, G.J.; Hildebrand, G.; Valsaraj, K.T.; Thibodeaux, L.J.; Springer, C. "Transport of chemical vapors through soil: A landfill cover simulation experiment". Journal of Hazardous Materials, 1992, 30(3), 333-342.

(163) Wu, J.; Harwell, J.H.; O'Rear, E.A. "Characterization by Ellipsometry of polymerized ultra-thin films formed in a two-dimensional solvent on an oxide surface". Colloids and Surfaces, 1987, 26, 155-169.

(164) Tertykh, V.A.; Yanishpolskii, V.V.; Panova, O.Y. "Covalent Attachment of Some Phenol Derivatives to the Silica Surface by Use of Single-stage Aminomethylation". J. Thermal Anal. Calorim., 2000, 62, 545-549.

(165) Pu, Q.; Su, Z.; Hu, Z.; Chang, X.; Yang, M. "Mercaptobenzothiazole-bonded silica gel as selective adsorbent for preconcentration of gold, platinum and palladium prior to their simultaneous inductively coupled plasma optical emission spectrometric determination". J. Anal. At. Spectrom1., 1998,13, 249-253.

(166) Soliman, E.M.; Mahmoud, M.E.; Ahmed, S.A. "Synthesis, characterization and structure effects on selectivity properties of silica gel covalently bonded diethylenetriamine mono- and bis-salicyaldehyde and naphthaldehyde Schiff,s bases towards some heavy metal ions". Talanta, 2001, 54, 243-253.

(167) Prado, A.G.; Airoldi, C. "Adsorption, preconcentration and separation of cations on silica gel chemically modified with the herbicide 2,4-dichlorophenoxyacetic acid". Anal. Chem. Acta., 2001, 432, 201-211.

(168) Gambero, A.; Kubota, L.T.; Gushikem, Y.; Airoldi, C.; Granjeiro, J.M.; Taga, E.M.; Alcˆantara, E.C. "On the Nature of The Liquid Expanded/Liquid Condensed Phase Transition in Monolayers of Polar Molecules". J. Colloid Interface Sci., 1997, 185, 313-315.

(169) Prado, A.S.; Airoldi, C. "Immobilization of the pesticide 2,4‐dichlorophenoxyacetic acid on a silica gel surface". Pest. Manag., Sci., 2000, 56, 419 - 424.

(170) Qhobosheane, M.; Santra, S.; Zhang, P.; Tan, W. "Biochemically functionalized silica nanoparticles". Analyst, 2001, 126, 1274-1278.

(171) Lynch, B.; Glennon, J.; Tröltzsch, C.; Menyes, U.; Pursch, M.; Albert, K. "A (−)Menthyl Bonded Silica Phase for Chiral Separations: Synthesis and Solid-State NMR Characterization". Anal. Chem.,1997, 69(9), 1756–1762.

(172) Chaimberg, M.; Parnas, R.; Cohen, Y. "Graft polymerization of polyvinylpyrrolidone onto silica". J. Appl. Polym. Sci., 1989, 37, 2921-2931.

(173) Nguyen, V.; Yoshida, W.; Cohen, Y. "Graft polymerization of vinyl acetate onto silica". J. Appl. Polym. Sci., 2003, 87, 300-310.

(174) Claude, B.; Michel, D.; Francois, M. "US Patent" 3,984, 1976, 349.

(175) Arnett, L.M.; Bechtold, M.F.; Benson, R.E. "US Patent" 2,728, 1955, 732.

(176) Seeber, G.; Brunner, P.; Buchmeiser, M.R.; Bonn, G.K. "Poly(7-oxanorborn-2-ene-5,6-dicarboxylate)-coated silica prepared by ring-opening metathesis polymerization for the selective enrichment of radioactive lanthanides". J. Chromatogr. A.,1999, 848, 193-202.

(177) Buchmeiser, M.R.; Mupa, S.M.; Bonn, G.K. "ROMP-Based, Highly Hydrophilic Poly(7-oxanorborn-2-ene-5,6-dicarboxylic acid)-Coated Silica for Analytical and Preparative Scale High-Performance Ion Chromatography". Chemistry of Materials, 1999, 11(6), 1533-1540.

(178) Buchmeiser, M.R.; Seeber, G.; Tessadri, R. "Quantification of Lanthanides in Rocks Using Succinic Acid-Derivatized Sorbents for On-Line SPE-RP-Ion-Pair HPLC". Anal. Chem., 2000, 72, 11, 2595–2602.

(179) Vlašánkova, R,; Otruba, V.; Bendl, J.; Fišera, M.; Kanický, V. "Preconcentration of platinum group metals on modified silica gel and their determination by inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry in airborne particulates". Talanta, 1999, 48, 839 - 846.

(180) Otruba, V.; Pivnička, J.; Kanický, V. "Separation and Preconcentration of Cr(VI) as Ion Associate Using Solid Phase Extraction". Collect. Czech. Chem. Commun., 2000, 65, 1865-1874.

(181) Hájková, J.; Kanický, V.; Otruba, V. "Preconcentration and Separation of Gold on Modified Silica Gel". Collect. Czech. Chem. Commun., 2000, 65, 1848-1864.

(182) Terada, K.; Matsumoto, K.; Taniguchi, Y. "Preconcentration of palladium(II) from water with thionalide loaded on silica gel". Anal. Chim. Acta., 1983, 147, 411-415.

(183) Terada, K.; Morimoto, K.; Kiba, T. "Preconcentration of silver(I), gold(III) and palladium(II) in sea water with p-(dimethylamino) benzylidene rhodanine supported on silica gel". Anal. Chim. Acta., 1980, 116, 127-135.

(184) Sutthivalyakit, P.; Ketturp, A. "Immobilization of 5-methylene-2-(2′-thiazolylazo)-anisole on silica and its application in preconcentration of palladium". Anal. Chim. Acta., 1985, 169, 331-337.

(185) Seshadri, Y.; Haupt, H.J. "Silica-immobilized 2-[(2-(triethoxysily)ethyl)thio]aniline as a selective sorbent for the separation and preconcentration of palladium". Anal. Chem., 1988, 60(1), 47–52.

(186) Hill, J.M. "Silica gel as an insoluble carrier for the preparation of selective chromatographic adsorbents: The preparation of 8-hydroxyquinonline substituted silica gel for the chelation chromatography of some trace metals". J. Chromatogr, 1973, 76, 455-458.

(187) Sugawara, K.F.; Weetall, H.H.; Schucker, G.D. "Preparation, properties, and applications of 8-hydroxyquinoline immobilized chelate". Anal. Chem., 1974, 46(4), 489-492.

(188) Weetall, H.H.; Weliky, N. "The coupling of biologically active molecules to insoluble polymers: antibody on cellulose". Biochimica et Biophysica Acta (BBA) - General Subjects, 1956, 107(124), 150-152.

(189) Fulcher, C.; Crowell, M.A.; Bayliss, R.; Holland, K.B.; Jezorek, J.R. "Synthetic aspects of the characterization of some silica-bound complexing agents". J. R. Anal. Chim. Acta, 1981, 129, 29-47.

(190) Marshall, M.A.; Mottolam, H.A. "Synthesis of silica-immobilized 8-quinolinol with (aminophenyl) trimethoxysilane". Anal. Chem., 1983, 55 (13), 2089–2093.

(191) Willie, S.N.; Tekgul, H.; Sturgeon, R.E. "Immobilization of 8-hydroxyquinoline onto silicone tubing for the determination of trace elements in seawater using flow injection ICP-MS". Talanta, 1998, 47, 439-445.

(192) Uibel, R.H.; Harris, J.M. "In Situ Raman Spectroscopy Studies of Metal Ion Complexation by 8-Hydroxyquinoline Covalently Bound to Silica Surfaces". Anal. Chem., 2002, 74(19), 5112–5120.

(193) Goswami, A.; Singh, A.K.; Venkataramani, B. "8-Hydroxyquinoline anchored to silica gel via new moderate size linker: synthesis and applications as a metal ion collector for their flame atomic absorption spectrometric determination". Talanta, 2003, 60, 1141-1154.

(194) Sturgeon, R.E.; Berman, S.S.; Willie, S.N.; Desaulniers, J.H. "Preconcentration of trace elements from seawater with silica-immobilized 8-hydroxyquinoline". Anal. Chem., 1981, 53(14), 2337–2340.

(195) Shahata, M.M. "Adsorption of Some Heavy Metal Ions by Used Different Immobilized Substances on Silica Gel". Arabian Journal of Chemistry, 2016, 9(6), 755 – 763.

(196) Shahata, M.M.; Kamal, M.M. "Material and method for removing heavy metal salts from water". Egyptian Patent, No. 28131, 2017.

How to Cite
Shahata, M. (2021). Poly (8-Hydroxyquinoline) Properties, Different Methods for Characterization, and New Applications for Different Uses: Review Article. European Journal of Applied Sciences, 9(1), 117-161. https://doi.org/10.14738/aivp.91.9409