Dyeing Properties of Vilangin Synthesized from Embelin on Cotton Fibre
DOI:
https://doi.org/10.14738/aivp.96.11308Keywords:
colour strength, characterization, embelin, vilanginAbstract
Semi synthesis involves the use of chemical compounds isolated from natural sources as the starting materials to produce other distinct compounds with added value and improved chemical properties. Most modified dyes have been synthesized through chemical modification to increase solubility and fastness properties of the dyes. A semi-synthetic dye (vilangin) has been obtained through chemical modification of embelin (a benzoquinone) isolated from Embelia schimperi berries crude extract, a plant-based dye. The vilangin dye was synthesized by condensation of embelin with formaldehyde in acetic acid solution., Their melting point and thin layer chromatography was done to determine purity. Characterization was done using Ultraviolet–Visible spectroscopy, Fourier Transform Infrared spectroscopy, Liquid chromatography Mass spectrometry and Nuclear Magnetic Resonance Spectroscopy. Embelin and the semi- synthesized dye were applied on cotton fabrics and colour fastness properties such as wash fastness, rubbing fastness, light fastness were evaluated. Embelin dye and vilangin dye exhibited similar colour strengths (K/S values) of 0.18 and 0.19 respectively. Use of mordants increased the colour strengths from 0.19 to 0.23 for the pre-mordanted cotton fibers ,the post-mordanted were in the range of 0.19-0.32 whereas the simultaneous mordanting showed better characteristics in the range of 0.27-0.52 for the vilangin dye. It has thus been established that the semi-synthetic dye possessed superior fastness properties compared to the parent embelin dye.
References
Phan, K., et al., The potential of anthocyanins from blueberries as a natural dye for cotton: A combined experimental and theoretical study. Dyes and Pigments, 2020: p. 108180.
Woodhead, A.L., B. Cosgrove, and J.S. Church, The purple coloration of four late 19th century silk dresses: a spectroscopic investigation. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2016. 154: p. 185-192.
Vettese Forster, S. and R.M. Christie, The significance of the introduction of synthetic dyes in the mid 19th century on the democratisation of western fashion. JAIC-Journal of the International Colour Association, 2013. 11.
Tamburini, D., et al., Exploring the transition from natural to synthetic dyes in the production of 19th-century Central Asian ikat textiles. Heritage Science, 2020. 8(1): p. 1-27.
Bayomie, O.S., et al., Novel approach for effective removal of methylene blue dye from water using fava bean peel waste. Scientific reports, 2020. 10(1): p. 1-10.
Xu, H.-M., et al., Development of laccase/graphene oxide membrane for enhanced synthetic dyes separation and degradation. Separation and Purification Technology, 2018. 204: p. 255-260.
Javaid, R. and U.Y. Qazi, Catalytic oxidation process for the degradation of synthetic dyes: an overview. International journal of environmental research and public health, 2019. 16(11): p. 2066.
Pandey, R., et al., Colouration of textiles using roasted peanut skin-an agro processing residue. Journal of Cleaner Production, 2018. 172: p. 1319-1326.
Harsito, C., et al., Enhancement stability and color fastness of natural dye: A review. Open Engineering, 2021. 11(1): p. 548-555.
Farooq, A., et al., Development of a novel method for natural dyeing of cotton fabrics using ultrasonic radiations and acacia bark. Journal of Natural Fibers, 2018. 15(5): p. 680-686.
Cooksey, C., The red insect dyes: carminic, kermesic and laccaic acids and their derivatives. Biotechnic & Histochemistry, 2019. 94(2): p. 100-107.
Arora, J., P. Agarwal, and G. Gupta, Rainbow of natural dyes on textiles using plants extracts: Sustainable and eco-friendly processes. Green and Sustainable Chemistry, 2017. 7(01): p. 35.
Savjani, K.T., A.K. Gajjar, and J.K.J.I.S.R.N. Savjani, Drug solubility: importance and enhancement techniques. 2012. 2012.
Atlabachew, M., et al., Single‐step isolation of embelin using high‐performance countercurrent chromatography and determination of the fatty acid composition of seeds of Embelia schimperi. 2017. 31(12): p. e4018.
Atlabachew, M., et al., Single‐step isolation of embelin using high‐performance countercurrent chromatography and determination of the fatty acid composition of seeds of Embelia schimperi. Biomedical Chromatography, 2017. 31(12): p. e4018.
Mahendran, S., et al., Synthesis and evaluation of analgesic and anti-inflammatory activities of most active free radical scavenging derivatives of Embelin—A Structure–Activity relationship. Chemical and Pharmaceutical Bulletin, 2011. 59(8): p. 913-919.
VASUDEVAN, T.J.J.o.s. and i. research, NATURAL HAIR DYES. 1996. 55(11): p. 885-887.
Panichayupakaranant, P., S. Tewtrakul, and S. Yuenyongsawad, Antibacterial, anti-inflammatory and anti-allergic activities of standardised pomegranate rind extract. Food Chemistry, 2010. 123(2): p. 400-403.
Balachandran, C., et al., Synthesis and medicinal properties of plant-derived vilangin. Environmental chemistry letters, 2013. 11(3): p. 303-308.
Khattab, T.A., et al., Textile dyeing industry: environmental impacts and remediation. 2020. 27(4): p. 3803-3818.
Karabulut, K., R.J.F. Atav, and Polymers, Dyeing of cotton fabric with natural dyes without mordant usage Part I: determining the most suitable dye plants for dyeing and UV protective functionalization. 2020. 21(8): p. 1773-1782.
Sutlović, A., et al., Optimization of dyeing process of cotton fabric with cochineal dye. 2020. 21(3): p. 555-563.
Chakraborty, L., P. Pandit, and S.R.J.J.o.C.P. Maulik, Acacia auriculiformis-A natural dye used for simultaneous coloration and functional finishing on textiles. 2020. 245: p. 118921.
Ayele, M., et al., Natural dyeing of cotton fabric with extracts from mango tree: A step towards sustainable dyeing. 2020. 17: p. 100293.
Manyim, S., et al., Dyeing of cotton fabric with Euclea divinorum extract using response surface optimization method. 2021.
Sadeghi-Kiakhani, M., et al., Ultrasound-assisted extraction of natural dyes from Hawthorn fruits for dyeing polyamide fabric and study its fastness, antimicrobial, and antioxidant properties. 2021. 23(6): p. 9163-9180.
Shrimali, H., et al., Fabrication and evaluation of a medicated hydrogel film with embelin from Embelia ribes for wound healing activity. 2019. 5(1): p. 1-10.
Kaur, V., et al., Isolation of embelin from and evaluation of its anti-cancer potential in Embelia ribes breast cancer. 2015. 1(1): p. 33-39.
Ondee, S., et al., Chemical Standardization and Anti-Proliferative Activity of Ardisia elliptica Fruit against the HCT116 Human Colon Cancer Cell Line. 2020. 25(5): p. 1023.
Aravindhan, R., et al., Synthesis, characterization and biological profile of metal and azo-metal complexes of embelin. 2014. 1(1): p. 69-79.
Shaikh, A., et al., Effect of Embelin Against Lipopolysaccharide‐induced Sickness Behaviour in Mice. 2016. 30(5): p. 815-822.
Badamaranahalli, S.S., et al., Embelin lipid nanospheres for enhanced treatment of ulcerative colitis–Preparation, characterization and in vivo evaluation. 2015. 76: p. 73-82.
Balachandran, C., et al., Synthesis and medicinal properties of plant-derived vilangin. 2013. 11(3): p. 303-308.
Bouzeko, I.L.T., et al., A new alkylbenzoquinone from Embelia rowlandii Gilg.(Myrsinaceae). 2019. 33(13): p. 1909-1915.
Mahendran, S., et al., Antioxidant, analgesic and anti-inflammatory properties of new ninhydrin adduct of embelin. 2011. 45(9): p. 547-551.
Shabbir, M., et al., Light fastness and shade variability of tannin colorant dyed wool with the effect of mordanting methods. 2019. 16(1): p. 100-113.
Wu, W., et al., Study of the aggregation behaviour of three primary reactive dyes via molecular dynamics simulations. 2020. 46(8): p. 627-637.
Gong, K., et al., Natural dyeing of merino wool fibers with Cinnamomum camphora leaves extract with mordants of biological origin: a greener approach of textile coloration. 2020. 111(7): p. 1038-1046.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2021 Margaret Koske
This work is licensed under a Creative Commons Attribution 4.0 International License.
