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European Journal of Applied Sciences – Vol. 10, No. 1

Publication Date: February 25, 2022

DOI:10.14738/aivp.101.11419. Brigui, O. J., Agbo, D. D. A., & Monnehan, G. A. (2022). Assessment of Natural Radioactivity in Gravel Samples Collected from Abidjan

District in Côte d’Ivoire. European Journal of Applied Sciences, 10(1). 126-134.

Services for Science and Education – United Kingdom

Assessment of Natural Radioactivity in Gravel Samples Collected

from Abidjan District in Côte d’Ivoire

BRIGUI Olkalé Jean-Claude

Laboratoire des Sciences de la Matière, de l’Environnement et de

l’Energie Solaire, UFR des Sciences des Structures de la Matière et

Technologie, Equipe de physique Nucléaire et Radioprotection

Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire

AGBO Djama Djoman Alfred

Laboratoire des Sciences de la Matière, de l’Environnement et de

l’Energie Solaire, UFR des Sciences des Structures de la Matière et

Technologie, Equipe de physique Nucléaire et Radioprotection

Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire

MONNEHAN Georges Alain

Laboratoire des Sciences de la Matière, de l’Environnement et de

l’Energie Solaire, UFR des Sciences des Structures de la Matière et

Technologie, Equipe de physique Nucléaire et Radioprotection

Université Félix Houphouët Boigny, Abidjan, Côte d’Ivoire

Autorité de Radioprotection, de Sûreté et Sécurité Nucléaires

Abidjan, Côte d’Ivoire

ABSTRACT

Gravel is one of the reference materials used in the construction sector and in

particular in Côte d'Ivoire. In this study, which appears to be one of the first works

on construction materials in Côte d'Ivoire, radiological measurements are carried

out on ten (10) samples of gravel from the district of Abidjan in order to evaluate

the activity concentration of natural radionuclides (226Ra, 232Th and 40K). The

measurements are made using the nuclear technique based on gamma

spectrometry with a GeHP detector. The average activity concentrations in the

samples were 5.98± 0.24 Bq.kg-1, 4.17± 1.65 Bq.kg-1 and 177.18± 3.50 Bq.kg-1 for

226Ra, 232Th and 40K respectively. These values, which were the first results

obtained, show that the natural radioactivity in these gravels is comparable to what

is usually measured in the same samples on a world scale, whose average limit

values are 35 Bq.kg-1, 30 Bq.kg-1 and 400 Bq. kg-1 (UNSCEAR, 2000). Therefore, the

radioactivity in these gravels does not pose an immediate health risk to the public.

Long-term effects can be avoided by simple precautionary measures.

Keywords : Gamma spectrometry Technique, gravel samples, District of Abidjan, activity

concentration

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Brigui, O. J., Agbo, D. D. A., & Monnehan, G. A. (2022). Assessment of Natural Radioactivity in Gravel Samples Collected from Abidjan District in

Côte d’Ivoire. European Journal of Applied Sciences, 10(1). 126-134.

URL: http://dx.doi.org/10.14738/aivp.101.11558

INTRODUCTION

Populations are subjected to environmental ionizing radiation from a wide variety of sources.

A part from the direct irradiation due to cosmic rays, human been is subjected to an irradiation

due to radioelements of natural origin contained in the ground, the rocks or the building

materials. Most of this radioactivity is due to elements of the uranium-238, thorium-232 and

potassium-40 series [1]. These radionuclides can cause adverse effects on human health,

particularly through external exposure to gamma radiation, ingestion or inhalation due to their

ionizing radiation on the body [2].

According to [3], the term “gravel” typically refers to pieces of crushed stone often basalt,

sandstone, or lime stone that are categorized by size, composition, color, or shape. Today; pea

gravel, river rock, and stone dust can all be considered gravel. There are many of applications

for these stone products in construction. The authors in [3] reported that from acting as fill

material or pipe bedding to making up foundations and roads, gravel is a versatile material that

comes in many shapes and sizes. Gravel is one of the reference materials in the construction

sector in Côte d'Ivoire. It is an important part in the different construction works. The risks

associated with construction materials can become important in the case of high levels of

radionuclides or chronic exposure over many years. This study is a preliminary assessment and

aims to assess the levels of naturally occurring radioactivity in samples of gravel used in the

Abidjan District in the various construction sectors.

MATERIALS AND METHODS

Study area

The District of Abidjan is located between latitudes 5°10 and 5°38 North and longitudes 3°45

and 4°21 West. Covering an area of 2119 km2, the District of Abidjan has a population density

of 2221 inhabitants / km2. Its population is estimated at 4,707,404 with a growth rate of 3.7%

[4]. Geologically, it belongs to the coastal sedimentary basin (figure 1).

Materials

Sampling and preparation equipment

The materials analyzed during this work are ten (10) samples of gravel. The equipment used in

the field for sample collection includes a Garmin (etrex) brand GPS to determine geographic

coordinates, shovels for manual collection and polythene sample bags. The laboratory

equipment used for sample preparation consists of a METTLER TOLEDO brand electronic

balance (Model: XP2001S, SNR; B044082756,12V / 2.25A) for different mass measurements of

the samples. There are also Marinelli beakers (SG 500) for the conditioning of the samples, an

oven for drying the samples, a ball mill and a sieve of 2 millimeters mesh.

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European Journal of Applied Sciences (EJAS) Vol. 10, Issue 1, February-2022

Services for Science and Education – United Kingdom

Figure 1: Map of the study area (District of Abidjan)

Equipment analysis

The radioactivity of the sand samples is measured using the gamma ray spectrometer installed

at the laboratory of the Radiation Protection Institute (RPI) of GAEC (Ghana). The measurement

chain includes the measurement chamber, a liquid nitrogen cooling system (77 K), a High purity

Germanium (HPGe) coaxial detector model GX 4020-7500 SL (Canberra brand ) and with a

resolution of 2 keV at 1332 keV (60Co).There are also a high voltage power supply (4000V)

essential for the collection of the quantity of electric charges deposited in the detector, a

cylindrical lead shielding 10 cm thick making it possible to reduce contributions of ambient

Scale

Study area

Hydrographi

c network

Atlantic ocean